Class 2 - Gases

2.1

2.1 Flammable gases

2.2

2.2 Non-flammable, non-toxic gases

2.3

2.3 Toxic gases

The heading of Class 2 covers pure gases, mixtures of gases, mixtures of one or more gases with one or more other substances and articles containing such substances.

A gas is a substance which:

  1. at 50 °C has a vapour pressure greater than 300 kPa (3 bar); or
  2. is completely gaseous at 20 °C at the standard pressure of 101.3 kPa.

Sub-classifications

The substances and articles of Class 2 are subdivided as follows:
1 Compressed gas: a gas which when packaged under pressure for carriage is entirely gaseous at -50 °C; this category includes all gases with a critical temperature less than or equal to -50 °C
2 Liquefied gas: a gas which when packaged under pressure for carriage is partially liquid at temperatures above -50 °C. A distinction is made between:
  1. High pressure liquefied gas: a gas with a critical temperature above -50 °C and equal to or below +65 °C; and
  2. Low pressure liquefied gas: a gas with a critical temperature above +65 °C;
3 Refrigerated liquefied gas: a gas which when packaged for carriage is made partially liquid because of its low temperature
4 Dissolved gas: a gas which when packaged under pressure for carriage is dissolved in a liquid phase solvent
5 Aerosol dispensers and receptacles, small, containing gas (gas cartridges)
6 Other articles containing gas under pressure
7 Non-pressurized gases subject to special requirements (gas samples)
8 Chemicals under pressure: liquids, pastes or powders, pressurized with a propellant that meets the definition of a compressed or liquefied gas and mixtures thereof
9 Absorbed gas: a gas which when packaged for carriage is adsorbed onto a solid porous material resulting in an internal receptacle pressure of less than 101.3 kPa at 20 °C and less than 300 kPa at 50 °C.

Groups

Substances and articles (except aerosols and chemicals under pressure) of Class 2 are assigned to one of the following groups according to their hazardous properties, as follows:
A asphyxiant
C corrosive
O oxidizing
F flammable
T toxic
TF toxic, flammable
TC toxic, corrosive
TO toxic, oxidizing
TFC toxic, flammable, corrosive
TOC toxic, oxidizing, corrosive
ADR European Agreement Concerning the International Carriage of Dangerous Goods by Road, ECE/TRANS/257 (Vol. 1), Economic Commission for Europe Inland Transport Committee, UNECE 2017